All CIPAC HandbooksIt should be noted that the year of publication of the handbooks is the year given on the title page. Due to an accidental slip the years on the title pages of the handbooks F and L on the CD-ROM are incorrect.
The correct years are:
Handbook
CIPAC Handbook B
Dodine 101
Page 1803:
Third sentence, change "RE 43.4" to: "RE 43.2"
CIPAC Handbook D
Hydrochloride
387Page 27:
Change the sentence: "(c) Determination. Pipette into a volumetric flask (50 ml) 2 ml…….maintained at
25 ± 1° C" to: "(c) Determination. Pipette into a volumetric flask (50 ml) 2 ml of this solution and add methanol (2 ml). Add DTNB solution (2 ml), mix, and make up to volume with buffer solution maintained at 25 ± 1° C."Phosalone 109 Page 141:
Change the CA chemical name of Phosalone from S-[6-chloro-2-oxo-3(2H)-benzoxazolyl)-methyl] O,O-phosphorodithioate to S-[(6-chloro-2-oxo-3(2H)-benzoxazolyl)methyl] O,O-diethyl phosphorodithioate.Thiobencarb 388 Pages 159 - 161:
Change the code for thiobencarb from 338 to 388.
CIPAC Handbook E
Maneb 61 Page 116:
At "2.1 CS2 evolution." delete reference to: "CIPAC D, p 179." At "2.4 Identification of amines." delete reference to: "CIPAC P 81, p 370."Maneb 61 Page 119:
At "4.Manganese." change reference to: "CIPAC 1A, p 1288" to: "CIPAC E, p 195."Phosphamidon
110Page 180:
Change the sentence: " Mobile phase buffer solution-wateracetonitrile-water, 170 + 170+ 135 + 25" to: "Mobile phase buffer solution-water-acetonitrile-methanol, 170 + 170+ 135 + 25"Triadimenol
398Page 224: Change the structural formula given to:
CIPAC Handbook F
MT 3
Specific Gravity...Page 20:
Under Note7, change: "Apparent density = Apparent SG × 0.99715× cm –3" to: "Apparent density = Apparent SG × 0.99700× cm –3"MT 22.1
ViscosityPage 75:
Dynamic viscosity
...It is expressed in Pascal second (Pa s) or in milli Pascal second (mPa s).Kinematic viscosity
... It is expressed in square metre per second (m²/s) or in square millimetre per second (mm²/s).
MT 22.1
ViscosityPage 76:
The units for the viscosity range and the viscosity minimum in table 1 should be read as mm²/s.MT 22.1
ViscosityPage 81:
The unit for the order of viscosity in table II should be read as mm²/s.
(vii) Calculation
The unit for the kinematic viscosity = mm²/s.MT 22.1 - 22.3
ViscosityPage 84:
Note 5: ....shall be accepted as 1.0020 mPa s and 1.0038 mm²/s, respectively.MT 41
Dilution stailityPage 131 ff
See the amended method description, which can be donloaded as a pdf-file hereMT 58
Dust Content...Page 173:
Add above APPARATUS (18th line) the section heading: "58.3 Sieve analysis"MT 58
Dust Content...Page 175:
Change section heading "58.3 Apparent Density…..etc" to: "58.4 Apparent Density…..etc"MT 162
Determination of
Ethylenethiourea
(ETU)Page 399: Change the structural formula given to:
MT 165
Ultraviolet
Absorption Test
for Evaluation...Page 412:
Change the sentence: "(a) Zineb, mancozeb, and mixtures of maneb with water soluble……..0.05 units (see Fig 51 a)." to: "(a) Zineb, mancozeb, and mixtures of maneb with water soluble……..0.05 units (see Fig 51 b)." and the sentence: "(b) Maneb, and mixtures of maneb……..of 0.1 to 0.7 units (see Fig 51 b)." to:"(b) Maneb, and mixtures of maneb……….0.5 units (see Fig 51 a)."MT 165
Ultraviolet
Absorption Test
for Evaluation...Page 413:
Change the caption of Figure 51a "Ultraviolet spectrum of zineb, mancozeb or mixtures of maneb with water-soluble zinc salts" to: "Ultraviolet spectrum of maneb with zineb, or mixtures of maneb with water-insoluble zinc salts"MT 165
Ultraviolet
Absorption Test
for Evaluation...Page 413:
Change the caption of Figure 51b "Ultraviolet spectrum of maneb with zineb, or mixtures of maneb with water-insoluble zinc salts" to: "Ultraviolet spectrum of zineb, mancozeb or mixtures of maneb with water-soluble zinc salts"MT 169
Tap Density of...Page 421:
Change the formula "m = n * D *20 g" to: "m = n *D *20 ml"MT 171
Dustiness of Granular ProductsPage 428 and CD-ROM Handbooks E to M:
Assessment of Dustiness: The corrected values are given below.
MT 172
Flowability, of WG...Page 430:
See the amended method description, which can be donloaded as a pdf-file here
Appendix C Page 462:
Change "DP Dispersible powder" to: "DP Dustable powder"
CIPAC Handbook H
Chlorsulfuron
391Page 93:
Under Calibration solutions. Change the sentence: "Weigh (to the nearest 0.1 mg) ……chlorsulfuron." to: "Weigh (to the nearest 0.1 mg) into a volumetric flask (100 ml) 100 mg chlorsulfuron standard (s mg)."Imidacloprid
582Page 186:
Under 2.3 1H-NMR, change "0.02 ± 0.02 g imidacloprid" to: "2 ± 0.02 g imidacloprid"Propazine 92 Page 233:
Under Internal standard solution, change: "14.0 ± 0.1 g" to: "4.0 ± 0.1 g"Sulfotep 198 Page 256:
Under OUTLINE OF MEHOD, delete: "C-18".Tebuconazole
494Page 265:
The retention time of dioctyl phthalate should "read "3.5 min" instead of "35 min"
CIPAC Handbook J
Pyridaben 583 Page 95:
Under Internal standard solution, change "…laurophenone (about 300 mg)." to: "…laurophenone (about 3000 mg)."MT 75.3
Determination
of pH ValuesPage 131:
(i): Line 7: Change the last two phrases as follow:
... Immerse the electrode into the liquid and immediately start the stopwatch (Note 7). Record the pH values after 1 and 2 minutes, without stirring during the measurement. If the two pH values differ by more than 0.1 pH units, record and report the pH value 10 minutes after immersing the electrode.
Page 132:
Note 7: When using an automatic pH meter, where the measurement stops automatically as soon as the pH changes are less than a pre-set drift value of 0.1 pH units/min, a measurement period of less than 10 min is acceptable and the resulting pH value should be reported.
CIPAC Handbook K
Dicamba 85. Page 34:
(d) Determination. Inject in duplicate 10 ul portions of the ....MT 187
Particle Size...Page 153:
The footnote should be read as ...Based on a method supplied by BASF AG, Germany.
CIPAC Handbook L
MT 190
Determination
of Release
Properties...Page 141:
Wrong: Internal standard solution. Weight into a volumetric flask dicyclohexyl phtalate (0.35mg), dissolve...
Correct: Internal standard solution. Weight into a volumetric flask dicyclohexyl phtalate (0.35g), dissolve...MT 192
Viscosity of
Liquids by
Rotational
ViscometryPage 145 - 146:
The published method did not contain the required description of the sample preconditioning.
The amended method will be published in the next Handbook.However, in this case the amended MT 192 can be exceptionally downloaded as a pdf-file here.
MT 193
Friability of tablets
Page 147 ff:
See the amended method description, which can be donloaded as a pdf-file here
CIPAC Handbook M
Azoxystrobin 571 Page 12:
Wrong: Fused silica, 25 m × 0.32 mm (i.d.) coated with CP-Sil 13CB phase, film thickness 0.12 μm (crosslinked 14% phenyl 86% dimethyl poly-siloxane).
Correct: Fused silica, 25 m × 0.32 mm (i.d.) coated with CP-Sil 13CB phase, film thickness 0.2 μm (crosslinked 14% phenyl 86% dimethyl poly-siloxane)Diquat 55 Page 69:
Wrong: Mobile phase B. Add diethylamine (2 ml) to acetonitrile (1000 ml) in a suitable flask. Mix well and degas before use.
Correct: Mobile phase B. Add diethylamine (2 ml) to methanol (1000 ml) in a suitable flask. Mix well and degas before usePyraclostrobin
657Page 172:
Wrong: Mobile phase water - acetonitrile - acetic acid, 750 + 250 + 1 (v/v)
Correct: Mobile phase acetonitrile - water - acetic acid, 750 + 250 + 1 (v/v)Remark: The definition of the mobile phase under "REAGENTS" on page 171 is correct.
last update 23.11.2011
